Irreversible thermodynamics of thermoelectric devices: from local framework to global description
نویسندگان
چکیده
Thermoelectricity is traditionally explained via Onsager's irreversible, flux-force framework. The coupled flows of heat and electric charge are modelled as steady-state flows, driven by the thermodynamic forces defined in terms gradients local, intensive parameters like temperature electrochemical potential. A thermoelectric generator a device with finite extension, its performance measured total power output entropy generation. These global quantities naturally expressed discrete or derived from their local counterparts. We analyze thermodynamics thermoelectricity relations. relations clearly show additional quadratic dependence driver flux on forces, corresponding to process Joule heating. discuss kinetic coefficients these prove that equality cross-coefficients similar property coefficients. Finally, we clarify differences between framework for energy conversion recently proposed minimally nonlinear irreversible model.
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ژورنال
عنوان ژورنال: Journal of Statistical Mechanics: Theory and Experiment
سال: 2021
ISSN: ['1742-5468']
DOI: https://doi.org/10.1088/1742-5468/ac0f68